Stresses due to Squeeze Flow between Particles Surrounded by an Electrolyte Solution with Application to Lithium-Ion Batteries*

Large stresses are induced during lithium-ion battery charging and discharging, termed intercalation and deintercalation stresses. Current models of the stresses in lithium-ion batteries in the literature seldom consider the influence of the interaction between the particles within the electrodes on the stress distribution. The particles within lithium-ion battery electrodes can undergo relative motion with relative velocities of different magnitudes and directions. One important mode of motion manifests itself as two particles approaching each other. The interaction is mediated by the electrolyte between the particles. The relative motion of the particles induces significant pressures and the primary objective of this work is to propose a source of mechanical stresses as a consequence of the dynamic squeezing motion as opposed to a static environment considered in the battery literature. Other applications in the biomedical field are also discussed.