Session U27: Correlated Electrons: Theory, Actinides, and Ising Systems

8:00 AM–10:48 AM, Thursday, March 13, 2008
Morial Convention Center - 219

Sponsoring Unit: DCMP
Chair: Makariy Tanatar, University of Sherbrooke

Abstract ID: BAPS.2008.MAR.U27.12

Abstract: U27.00012 : Investigation of Dipole-Forbidden $d-d$ Excitations in Strongly Correlated Transition-Metal Oxides Using Higher-Order Multipole, Non-resonant Inelastic X-Ray Scattering

10:12 AM–10:24 AM

Preview Abstract

Authors:

  B.C. Larson
    (ORNL)

  J.Z. Tischler
    (ORNL)

  C.-L. Yeh
    (Tamkang Univ., Taiwan)

  C.-C. Lee
    (BNL)

  Wei Ku
    (BNL)

We have shown that quadrupole and higher order multipole non-resonant inelastic x-ray scattering (NIXS) at large wavevectors, $q$, provides direct access to dipole-forbidden $d-d$ excitations (Larson et al. \textit{Phys. Rev. Lett.} \textbf{99}, 026401 (2007)). NIXS measurements using the XOR/UNI beamline at the APS have shown that the large-$q $intensity of on-site excitons in NiO and CoO is highly anisotropic in $q$ and dominates the energy loss spectrum. Energy-resolved Wannier function analyses have shown that the anisotropies, including a nodal direction for NiO, provide direct information on the point-group symmetry of the particle-hole wave functions for transition-metal oxides. The interpretation of these large-$q$ NIXS measurements will be discussed in connection with energy-resolved Wannier function analyses and LDA+$U$ dynamical response calculations. Implications for the extension of such investigations to manganite systems will be considered.

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2008.MAR.U27.12