Session H13: Colloid and Polymer Interfaces
11:15 AM–1:39 PM, Tuesday, March 14, 2006
Baltimore Convention Center Room: 305
Sponsoring Unit:
DCP
Chair: Hai-Lung Dai, University of Pennsylvania
Abstract ID: BAPS.2006.MAR.H13.8
Abstract: H13.00008 : Thermal response of polymer coated colloidal diffusion near surfaces
12:39 PM–12:51 PM
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Abstract 
Authors:
Stephen Anthony
Huilin Tu
Liang Hong
Paul Braun
Steve Granick
(Departments of Chemistry and of Material Science, University of Illinois)
Thermally responsive poly(/N/-isopropylacrylamide) (PNIPAAm) tethered silica particles represent a potential building block for new materials. For this research, Surface-initiated Atom Transfer Radical Polymerization (ATRP) was chosen for its ability to generate well defined, homogeneous polymer brushes on silica nanoparticles and surfaces. Phase contrast optical microscopy was used along with single particle tracking methods to characterize the motion of these particles in suspension as well as close to brush modified surfaces. Temperature dependence experiments reveal that increased temperature decreases the radius of the particles. Additionally, heating may trigger a transition from ``sticky'' surfaces to ``slippery'' surfaces. Below LCST, swelled PNIPAAm chains may interdigitate and slow down particle motion. Thermal hysteresis was also apparent; kinetic trapping of particles resulted in the retention of an immobilized population upon cooling. Furthermore, the analysis of the diffusion dynamics also implies interparticle interactions and particle-surface interactions. Understanding the kinetics of this complex fluid system facilitates the design and control of novel materials.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2006.MAR.H13.8