### Session H13: Colloid and Polymer Interfaces

11:15 AM–1:39 PM, Tuesday, March 14, 2006
Baltimore Convention Center Room: 305

Sponsoring Unit: DCP
Chair: Hai-Lung Dai, University of Pennsylvania

Abstract ID: BAPS.2006.MAR.H13.7

### Abstract: H13.00007 : Experimental two-point microrheology of two-dimensional systems

12:27 PM–12:39 PM

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#### Authors:

Vikram Prasad
Eric Weeks
(Emory University)

Microrheology is often used to determine the bulk viscoelasticity of materials such as polymer solutions, by tracking the diffusion of tracer particles. For heterogeneous materials, where single particle microrheology breaks down, a modified technique known as two-point microrheology has been established where motions of particles with varying spatial separations are correlated. In 3-d systems, this correlated motion decays as 1/R, and can be used to identify the long wavelength modes in the system, and therefore the bulk viscoelasticity. For 2-d systems, theory has predicted a logarithmic decay, but to date, this prediction has gone untested. We look at the correlated motions of colloidal particles in two types of quasi 2-d systems (protein molecules at an air-water interface, and thin soap films), and observe a transition from 3-d to 2-d, by continuously varying the Boussinesq number, B$_{0}$ = ($\eta _{s}$/$\eta$a) from 0 to $\infty$ , where $\eta _{s}$ is the surface viscosity, $\eta$ is the bulk viscosity, and a is the size of the colloidal particle. The experimental results are compared to theory, and consequences for microrheology at interfaces are discussed.

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2006.MAR.H13.7