Bulletin of the American Physical Society
APS March Meeting 2023
Volume 68, Number 3
Las Vegas, Nevada (March 5-10)
Virtual (March 20-22); Time Zone: Pacific Time
Session F13: Emerging Principles and New Developments in Non-Equilibrium Thermodynamics, Natural Selection and Chemical Reaction Networks
8:00 AM–10:24 AM,
Tuesday, March 7, 2023
Room: Room 238
Sponsoring
Unit:
DBIO
Chair: William Cannon, Pacific Northwest Natl Lab
Abstract: F13.00001 : Statistical Thermodynamics and Data ad Infinitum
8:00 AM–8:36 AM
Presenter:
Ying-Jen Yang
(Stonybrook University)
Authors:
Hong Qian
(University of Washington)
Ying-Jen Yang
(Stonybrook University)
Asymptotically-equivalent models are also found by the Maximum Caliber Principle. With a novel derivation of Maximum Caliber, conceptual differences between the two principles are clarified. The emergent thermodynamics in the data infinitus limit has a mesoscopic origin from the Maximum Caliber. In the canonical probabilistic models of Maximum Caliber, the variances of the observables and their conjugated forces satisfy the asymptotic thermodynamic uncertainty principle, which stems from the reciprocal-curvature relation between ``entropy'' and ``free energy'' functions in the theory of large deviations. The mesoscopic origin of the reciprocality is identified. As a consequence of limit theorems in probability theory, the phenomenological statistical thermodynamics is universal without the need of mechanics.
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