2023 APS March Meeting
Volume 68, Number 3
Las Vegas, Nevada (March 5-10)
Virtual (March 20-22); Time Zone: Pacific Time
Session CCC08: V: General Physics VI
3:00 PM–5:00 PM,
Wednesday, March 22, 2023
Room: Virtual Room 8
Chair: Kaveh Delfanazari, University of Glasgow
Abstract: CCC08.00010 : Raman signatures of spin-phonon coupling and quadratic band touching state in Pyrochlore Iridates (Sm1-xBix)2Ir2O7*
4:48 PM–5:00 PM
Abstract
Presenter:
Rosalin Mohanty
(Indian Institute of Science Bangalore)
Author:
Rosalin Mohanty
(Indian Institute of Science Bangalore)
The 5d transition metal oxides stand at the crossroad of strongly correlated systems where the SOC and the coulomb interaction compete at the same energy scale. In 5d Iridates this is further enhanced by the crystal field interaction that splits the t2g orbital and leaves the system in a low spin state (jeff=1/2). Among the iridates pyrochlore Iridates A2Ir2O7 (A=Y, Bi, and rare earth elements) have attracted much scientific attention as they potentially show various exotic phenomena and topologically non-trivial ground states. The SOC dominant Dzyaloshinskii-Moriya interaction competes with the inherent geometric spin-frustration giving rise to a non-co-linear “all-in or all-out” (AIAO) antiferromagnetically ordered ground state with broken time-reversal symmetry. The delicate relation between metal-insulator transition (MIT) and AIAO magnetic ordering in the 5d-pyrochlore iridates has provided a fated goal to search for the fingerprints of exotic states of matter in these geometrically frustrated systems. Here we use Raman spectroscopy to investigate the temperature dependence of phonons and magnetic as well as electronic background in (Sm1-xBix)2Ir2O7 samples. While both Bi2Ir2O7 and Sm2Ir2O7 stabilize in pyrochlore structure: the former is a correlated metal, and the latter is a Weyl Semi-metal (WSM) candidate with concomitant MIT near ~120 K. A strong spin-phonon coupling, and magnetic-order induced phonon renormalization is observed near magnetic transition temperature TN for samples with x≤0.035. Phonon anomalies at a scaling temperature much lower than TN are observed (for x≤0.02) and are possibly correlated with a crossover to the WSM state. An underlying broad scattering continuum attributed to pronounced spin-spin correlation is observed below TN for pure Sm2Ir2O7. We observe signatures of quadratic band touching (QBT) in x=0.05 and 0.10 samples in terms of a broad electronic continuum at low temperatures corroborating the inferences from transport measurements.
*Department of Science and Technology, India