Nonreciprocal directional dichroism at telecom wavelengths*

Magnetoelectrics with ultra-low symmetry and spin-orbit coupling are well known to display a number of remarkable properties including nonreciprocal directional dichroism. As a polar and chiral magnet, Ni₃TeO₆is predicted to host this effect in three fundamentally different configurations, although only two have been experimentally verified. Inspired by the opportunity to unravel structure-property relations related to such a unique light-matter interaction, we combined magneto-optical spectroscopy and first principles calculations to reveal nonreciprocity in the toroidal geometry and compared our findings with those measured in the chiral configurations. We find that formation of Ni²⁺ toroidal moments is responsible for the largest effects near 1.1 eV - a tendency that is captured by our microscopic model and computational implementation. At the same time, we demonstrate deterministic control of nonreciprocal directional dichroism in Ni₃TeO₆ across the entire telecom wavelength range. This discovery will accelerate the development of photonics applications that take advantage of unusual symmetry characteristics.