Bulletin of the American Physical Society
APS March Meeting 2022
Volume 67, Number 3
Monday–Friday, March 14–18, 2022; Chicago
Session F60: Correlated States I
8:00 AM–10:36 AM,
Tuesday, March 15, 2022
Room: Hyatt Regency Hotel -DuSable C
Chair: Andrey Baydin, Rice University
Abstract: F60.00004 : Electron-Lattice Coupling in 2D Transition Metal Dihalides MX2 and Trihalides MX3*
9:00 AM–9:12 AM
Presenter:
Alexandru Bogdan Georgescu
(Northwestern University)
Authors:
Alexandru Bogdan Georgescu
(Northwestern University)
Andrew J Millis
(Columbia University)
James M Rondinelli
(Northwestern University)
Here we examine the role of trigonal symmetry breaking and its electronic effects on correlated 2D van der Waals dihalides and trihalides MX2 and MX3, with M a transition metal and X a halogen ligand. We show that the 2D structure of these layered materials gives an inherent trigonal symmetry breaking to the transition metal d orbital manifold [1]. It is at most a 2-2-1 degeneracy, which can be controlled via changes in the ligand-ligand bond lengths, and inter-layer distances. We show that this physics is key to understanding the insulating state of materials in this class and discuss possible new exotic states in this class of materials.
*This research was supported in part by the National Science Foundation (NSF) under DMREF Award DMR1729303. The information, data, or work presented herein was funded in part by the Advanced Research Projects Agency-Energy (ARPA-E), U.S. Department of Energy, under Award Number DE-AR0001209.AJM is supported in part by Programmable Quantum Materials, an Energy Frontier Research Center funded by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES), under award DE-SC0019443. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. The Flatiron Institute is a division of the Simons Foundation.
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