Sound Speed in Shock-Compressed Iron up to 3 TPa*

The formation of terrestrial planets involves high-velocity impacts of iron-rich planetesimals in the later stages of accretion. The distribution of iron and other highly siderophile elements within the resulting planets depends on the thermodynamic evolution of the heated material after pressure release from the shock states produced by the impact. Sound speed is a critical thermodynamic property that provides information about how a material evolves after isentropic release from the shock state, and is directly connected to other thermodynamic derivatives such as the bulk modulus, Gruneisen parameter, and specific heat. We report sound speed measurements in iron shocked from 500 GPa up to 3000 GPa. Steady shocks were produced simultaneously in the iron sample and a sound speed-reference (alpha-quartz) using a pedestal laser pulse shape. Pressure perturbations were then launched simultaneously through the sample and reference by specially-tailored laser power modulations. Sound speed was deduced using the arrival time of the perturbation sequence at the shock front after emerging into a transparent window using high-precision velocimetry. Our results show the sound speed in shocked iron is less than 10% higher than recent isentrope measurements of the sound speed at 20 g/cc. The proximity of the Hugoniot to the isentrope sound speed, consistency with iron release measurements, and implications for impact vaporization of iron will be discussed.