APS March Meeting 2016
Volume 61, Number 2
Monday–Friday, March 14–18, 2016;
Baltimore, Maryland
Session C36: Soft Colloids: From Single Particle Properties to Bulk Phase Behavior and Dynamics
2:30 PM–5:30 PM,
Monday, March 14, 2016
Room: 339
Sponsoring
Units:
GSOFT DPOLY
Chair: Alberto Fernandez-Nieves, Georgia Institute of Technology
Abstract ID: BAPS.2016.MAR.C36.4
Abstract: C36.00004 : Soft particles with anisotropic interactions*
3:06 PM–3:42 PM
Preview Abstract
Abstract
Author:
Peter Schurtenberger
(Lund University)
Responsive colloids such as thermo- or pH-sensitive microgels are ideal model systems to investigate the relationship between the nature of interparticle interactions and the plethora of self-assembled structures that can form in colloidal suspensions. They allow for a variation of the form, strength and range of the interaction potential almost at will. While microgels have extensively been used as model systems to investigate various condensed matter problems such as glass formation, jamming or crystallization, they can also be used to study systems with anisotropic interactions. Here we show results from a systematic investigation of the influence of softness and anisotropy on the structural and dynamic properties of strongly interacting suspensions. We focus first on ionic microgels.\footnote{ P. Holmqvist, P.S. Mohanty, G. Nägele, P. Schurtenberger, and M. Heinen, Phys. Rev. Lett. 109, 048302 (2012)} \footnote{ J. Riest, P. Mohanti, P. Schurtenberger, and C. N. Likos, Z. Phys. Chem. 226, 711 (2012)} Due to their large number of internal counterions they possess very large polarisabilities, and we can thus use external electrical ac fields to generate large dipolar contributions to the interparticle interaction potential. This leads to a number of new crystal phases, and we can trigger crystal-crystal phase transitions through the appropriate choice of the field strength.\footnote{ S. Nöjd, P. S. Mohanty, P. Bagheri, A. Yethiraj and P. Schurtenberger, Soft Matter 9, 9199 (2013)} \footnote{ P. S. Mohanty, P. Bagheri, S. Nöjd, A. Yethiraj and P. Schurtenberger, Phys. Rev. X 5, 011030 (2015)}
We then show that this approach can be extended to more complex particle shapes \footnote{ J. J. Crassous, A. M. Mihut, L. K. Månsson, and P. Schurtenberger, Nanoscale 7, 15971-15982 (2015).}
\footnote{ Linda K. Månsson, Jasper N. Immink, Adriana M. Mihut, Peter Schurtenberger, and Jérôme J. Crassous, Faraday Discussions 181, 49 (2015).}
in an attempt to copy nature’s well documented success in fabricating complex nanostructures such as virus shells via self assembly.\footnote{ J. J. Crassous, A. M. Mihut, E. Wernersson, P. Pfleiderer, J. Vermant, P. Linse, and P. Schurtenberger, Nature Communications 5:5516 doi: 10.1038/ncomms6516 (2014)}
*European Research Council (ERC-339678-COMPASS)
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2016.MAR.C36.4