Plasmonic electron injection drives ultrafast phase transition by catastrophic phonon collapse II: theory*

The ultrafast photo-induced phase transition in VO$_{2}$ is promising for data storage and sensing applications. Our experimental work (the previous talk) shows that in a Au/VO$_{2}$ hybrid nanostructure, electrons excited in the Au photocathode by an ultrafast laser trigger the insulator-to-metal transition in VO$_{2}$. Here we report first-principles density-functional calculations showing that the collapse of a 6 THz optical phonon, corresponding to a twisting motion of V atoms, is responsible for the ultrafast phase transition. Above a concentration threshold, we find that injected electrons from Au induce collapse of the VO$_{2\, }$phonon, which stimulates the monoclinic-to-rutile structural phase transition. We also show that hole-doping can induce the same effect. The abrupt change of the critical phonon results from the weakening of the V-V bonds induced by the combined flux of injected electrons and holes. Thus, our results explain the experimental finding of plasmonic-electron-driven ultrafast phase transition and represent a step towards manipulating the photo-induced phase transition by surface modification.