APS March Meeting 2011
Volume 56, Number 1
Monday–Friday, March 21–25, 2011;
Dallas, Texas
Session L23: Focus Session: Search for New Superconductors II: Towards Theoretical Design
2:30 PM–5:30 PM,
Tuesday, March 22, 2011
Room: D165
Sponsoring
Unit:
DMP
Chair: Philip Phillips, University of Illinois
Abstract ID: BAPS.2011.MAR.L23.4
Abstract: L23.00004 : Why positive hole carriers and negatively charged planes are conducive to high temperature superconductivity
3:06 PM–3:42 PM
Preview Abstract
Abstract
Author:
J.E. Hirsch
(University of California San Diego)
The vast majority of superconducting materials have positive Hall
coefficient in the normal state, indicating that hole carriers
dominate the
normal state transport. This was noticed even before BCS theory,
and has
been amply confirmed by materials found since then: the sign of
the Hall
coefficient is the strongest normal state predictor of
superconductivity. In
the superconducting state instead, superfluid carriers are always
electron-like, i.e. negative, as indicated by the fact that the
magnetic
field generated by rotating superconductors is always parallel,
never
antiparallel, to the body's angular momentum (``London moment'').
BCS theory
ignores these facts. In contrast, the theory of hole
superconductivity,
developed over the past 20 years (papers listed in
http://physics.ucsd.edu/$\sim $jorge/hole.html) makes charge
asymmetry the
centerpiece of the action. The Coulomb repulsion between holes is
shown to
be smaller than that between electrons, thus favoring pairing of
holes, and
this fundamental electron-hole asymmetry is largest in materials
where the
conducting structures have \textit{excess negative charge}, as is
the case in the cuprates, arsenides and
MgB$_{2}$. Charge asymmetry implies that superconductivity is
driven by
lowering of kinetic energy, associated with expansion of the carrier
wavefunction and with \textit{expulsion of negative charge} from
the interior to the surface of the material,
where it carries the Meissner current. This results in a macroscopic
electric field (pointing outward) in the interior of
superconductors, and a
macroscopic spin current flowing near the surface in the absence
of external
fields, a kind of macroscopic zero point motion of the superfluid
(spin
Meissner effect). London's electrodynamic equations are modified
in a
natural way to describe this physics. It is pointed out that a
dynamical
explanation of the Meissner effect \textit{requires} radial
outflow of charge in the
transition to superconductivity, as predicted by this theory and not
predicted by BCS. The theory provides clear guidelines regarding
where new
higher T$_{c}$ superconductors will and will not be found.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2011.MAR.L23.4