Bulletin of the American Physical Society
77th Annual Gaseous Electronics Conference
Monday–Friday, September 30–October 4 2024; San Diego, California
Session GR2: Plasma Chemistry on Liquids
10:00 AM–12:00 PM,
Thursday, October 3, 2024
Room: Great Room 6-8
Chair: Hoang Nguyen, UNIVERSITY OF NOTRE DAME
Abstract: GR2.00006 : A pH and conductivity-based method for fast and accurate NOx- estimate in plasma-treated water*
11:30 AM–11:45 AM
Presenter:
Jovana Petkovic
(Eindhoven University of Technology)
Authors:
Jovana Petkovic
(Eindhoven University of Technology)
Robin van de Wege
(Eindhoven University of Technology)
Jente Wubs
(Leibniz Institute for Plasma Science and Technology (INP))
Olivier Van Rooij
(Eindhoven University of Technology)
Jeroen van Oorschot
(Eindhoven University of Technology)
Tom Huiskamp
(Eindhoven University of Technology)
Ana Sobota
(Eindhoven University of Technology)
The number of plasma applications have had growth in recent years, making them an increasingly valuable and relevant technology in various fields. Plasma is applied directly or to different mediums that can later be used for different applications.
During water treatment, reactive oxygen and nitrogen species (RONS) are created and dissolved in water, resulting in a conductive solution. Their interaction mechanisms make PTW a chemically active solution for different treatments. Accurately estimating the species created during plasma treatment is critical for tailoring the treated water to different applications.
Following these species can be done in many ways, including strips, colorimetry, luminescence, absorption spectroscopy, and others. While some methods offer fast estimate of RONS, they often lack accuracy and more complex methods require expensive equipment and more time. This is why new accurate methods to follow the species are of high importance.
Conductivity and pH are parameters often followed in PTW research. The new proposed method utilizes pH and conductivity measurements by using Kohlrausch’s law of independent ion migration with the assumption that the main charged species in the water are H+ and NOx-. By using these specific PTW parameters, we can accurately and rapidly determine the concentrations of NOx- species up to 1mM. The new method shows consistent results with those achieved using UV absorption spectroscopy, proving the method both fast and accurate.
*This publication is part of a TKI Project (WASPD), NWO Project (TTW-17183), TU/e-UU-UMCU Alliance program. The work is associated with COST Actions PlAgri CA19110 and PlasTher CA20114.
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