### Session Z20: Invited Session: Optical Processes in Nitrides and Other Wide-Band-Gap Semiconductors

11:15 AM–2:15 PM, Friday, March 2, 2012
Room: 253C

Chair: Joel Ager, Lawrence Berkeley National Laboratory

Abstract ID: BAPS.2012.MAR.Z20.2

### Abstract: Z20.00002 : Loss mechanisms in nitrides

11:51 AM–12:27 PM

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#### Author:

Chris Van de Walle
(Materials Department, University of California, Santa Barbara)

Indium gallium nitride alloys are successfully being used for light emitting diodes (LEDs) and laser diodes (LDs) in the green to ultraviolet part of the optical spectrum. These devices are the key enablers to Solid-State Lighting, which promises to significantly cut electricity consumption. Applications are still limited, however, by the declining efficiency of LEDs at high currents (droop'') and by absorption losses of undetermined origin in LDs. Several mechanisms have been suggested as the cause of this efficiency loss, such as Auger recombination and free carrier absorption. Experimentally it is very difficult to discriminate between different nonradiative processes. We have therefore addressed the loss mechanisms based on state-of-the-art first-principles computational theory. We use ab initio wave functions and bands that are accurate throughout the entire Brillouin zone (as opposed to k.p band structures). For Auger recombination we find that both electron-electron-hole and hole-hole-electron processes contribute, and that indirect processes assisted by alloy scattering and by electron-phonon coupling dominate. The magnitude of the resulting Auger coefficient indicates that Auger recombination is indeed responsible for the efficiency reduction at high carrier densities. Strategies for overcoming this limitation will be discussed. For free-carrier absorption, the relevant optical processes are again indirect. We determine the optical absorption coefficient and the corresponding photon mean free path as a function of carrier concentration. The computed values indicate that the effect is weak in LEDs but constitutes an important loss mechanism in LDs.

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2012.MAR.Z20.2