### Session Y20: Glassy and Amorphous Materials

8:00 AM–10:36 AM, Friday, March 19, 2010
Room: C120-122

Chair: Frances Hellman, University of California, Berkeley

Abstract ID: BAPS.2010.MAR.Y20.9

### Abstract: Y20.00009 : Anomalous Crystal Growth In Supercooled OTP On Temperature Cycling

9:36 AM–9:48 AM

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#### Authors:

Stephen C. Hall
(Pacific University)

Sean Lindsay
(Pacific Univeristy)

It has been previously observed [1] that when the fragile glass former o-terphenyl (OTP) is supercooled to -23 $^{\circ}$C, well below its normal freezing temperature but above its glass transition temperature, an anomalous growth mode appears indicated by a sudden increase in the crystal growth velocity. We report observations of this anomalous crystal growth when the temperature is raised briefly above the apparent transition temperature and then cooled back down. We find that when the temperature is raised to -20.5 $^{\circ}$C or less the original anomalous growth continues to grow, apparently uninterrupted. When the temperature is raised above -19 $^{\circ}$C the original anomalous growth does not continue to grow, although new anomalous growth nucleates. One interpretation of these results is that the transition temperature for the anomalous growth is around -20 $^{\circ}$C. \\[4pt] [1] M. Hatase, M. Hanaya, and M. Oguni, J. Non-Cryst. Solids \underline{333}, 129 (2004)

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2010.MAR.Y20.9