Session Y19: Focus Session: Polymer Colloids: Dynamics
8:00 AM–10:48 AM, Friday, March 19, 2010
Room: B118-B119
Sponsoring Units:
DPOLY DCMP
Chair: Ken Schweizer, University of Illinois, Urbana-Champaign
Abstract ID: BAPS.2010.MAR.Y19.8
Abstract: Y19.00008 : Connecting nanoscale motion and rheology of gel-forming colloidal suspensions
9:48 AM–10:00 AM
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Abstract 
Authors:
Hongyu Guo
(Physics, Johns Hopkins University)
Subramanian Ramakrishnan
(Chemical and Biomedical Engineering, Florida State University)
James Harden
(Physics, University of Ottawa)
Robert Leheny
(Physics, Johns Hopkins University)
We report a combined x-ray photon correlation spectroscopy (XPCS) and rheometry study of the evolution of concentrated suspensions of nanometer-scale colloids undergoing gelation and aging. The suspensions are comprised of silica colloids, 45 nm in diameter, stabilized with octadecyl-hydrocarbon chains in decalin at colloidal volume fractions near 0.20. At low temperature, the solvent quality is poor for the octadecyl chains, leading to a weak, temperature-dependent, short-range attraction between the colloids that drives a reversible gel transition. Following a quench through this transition, the shear modulus grows rapidly as a function of time after an extended induction period. The intermediate scattering function measured with XPCS displays two features, a plateau value that provides information about constrained local dynamics in the gel and a terminal relaxation time that provides information about relaxation of residual stress. From the wave-vector dependence of the plateau value, a localization length can be extracted. Except at early times, the relationship between the localization length and the shear modulus agrees quantitatively with the prediction of Chen and Schweitzer based on a simplified mode coupling theory.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2010.MAR.Y19.8