Session A20: Focus Session: Carbon Nanotubes: Functionalization and Growth
8:00 AM–11:00 AM, Monday, March 15, 2010
Room: C120-122
Sponsoring Unit:
DMP
Chair: Jeff Blackburn, National Renewable Energy Laboratory
Abstract ID: BAPS.2010.MAR.A20.5
Abstract: A20.00005 : Carbon Nanotube/CdSe Nanoparticle Hybrid Materials: Synthesis and Optical Properties
9:12 AM–9:24 AM
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Abstract 
Authors:
Austin Akey
(Columbia University)
Chenguang Lu
(Columbia University)
Wei Wang
(Columbia University)
Irving Herman
(Columbia University)
Carbon nanotubes present remarkable opportunities for construction of advanced nanomaterials with uniques properties, for use in sensors and optoelectronic device applications. Chemical attachment of nanoparticles to nanotubes has thus far resulted in low coverage; direct nucleation of particles on the tube sidewalls leads to a loss of control over particle size and monodispersity. We report the synthesis of novel heterostructures composed of single-walled carbon nanotubes and chemically attached, monodisperse cadmium selenide nanoparticles. The hybrid material is stable and resists aggregation; TEM and SEM characterization shows the nanotubes to be densely covered in nanoparticles. The nanoparticles used range in size from 3.5 to 6.0 nm in diameter, and exhibit strong quantum confinement. The hybrid materials are being investigated in the interest of finding new optical and/or electronic properties, which has lead to the observation of an anomalousmall Stokes shift in the photoluminescence. Results of ultrafast optical spectroscopy measurements on this phenomenon will be presented.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2010.MAR.A20.5