Session H19: Solid Amorphous Polymers
8:00 AM–11:00 AM, Tuesday, March 17, 2009
Room: 320
Sponsoring Unit:
DPOLY
Chair: Sergei Nazarenko, University of Southern Mississippi
Abstract ID: BAPS.2009.MAR.H19.11
Abstract: H19.00011 : Strain Hardening in Bidisperse Polymer Glasses
10:24 AM–10:36 AM
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Abstract 
Authors:
Mark O. Robbins
(Johns Hopkins University)
Robert S. Hoy
(Materials Research Laboratory, University of California, Santa Barbara)
The connections between glassy and rubbery strain hardening have been a matter of great controversy in recent years. Recent experiments and our earlier simulations have suggested that the hardening modulus $G_R$ is proportional to the entanglement density in glasses, as it is to the crosslink density in rubbers. In this work we present more extensive studies of strain hardening in bidisperse glasses and its relation to microscopic conformational changes. The mixtures contain chains of very different lengths but equivalent chemistry. $G_R$ does not scale simply with the entanglement density. Instead it obeys a simple mixing rule, with $G_R$ equal to the volume fraction weighted average of the moduli of the two pure components. As in recent studies of monodisperse systems (R. S. Hoy and M. O. Robbins, Phys. Rev. Lett. \textbf{99}, 117801 (2007)), the stress is directly correlated to the degree of chain orientation. Chains of a given length undergo almost the same degree of alignment in pure systems and mixtures, explaining why the simple mixing rule applies. The connection to recent analytic theories by K. Chen and K. S. Schweizer (PRL, in press) will be discussed.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2009.MAR.H19.11