Session B20: Focus Session: Polymers and Energy: Photovoltaics, Fuel Cells, Batteries I
11:15 AM–2:15 PM, Monday, March 16, 2009
Room: 321
Sponsoring Unit:
DPOLY
Chair: Bumjoon Kim, Korea Advanced Institute of Science and Technology
Abstract ID: BAPS.2009.MAR.B20.7
Abstract: B20.00007 : Controlling Photovoltaic Loss: Recombination of Dissociated Electrons and Holes in Organic Solar Cells
12:51 PM–1:03 PM
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Abstract 
Authors:
Zhihua Xu
Huidong Zang
Bin Hu
This presentation reports the studies of charge-transfer complex states formed from the recombination of dissociated electrons and holes at the donor-acceptor interfaces in bulk-heterojunction organic solar cells based on magnetic field effects of photocurrent. Our studies indicate that the formation of charge-transfer complex states is determined by the competition between Coulombic attraction and electrical drifting. Externally, applying electric field can clearly decrease the density of charge-transfer complex states through electrical drifting. Internally, morphology can change the competition between Coulombic attraction and electric drifting through dielectric fields and charge mobilities, and consequently affects the formation of charge-transfer complex states. As a result, changing internal dielectric fields and charge mobilities through internal Coulomb interaction and electrical drifting presents as two mechanisms to control the formation of charge-transfer complex states towards the improvement of photovoltaic efficiencies in organic bulk-heterojunction solar cells.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2009.MAR.B20.7