Session B39: Focus Session: Materials and Applications for Solar Energy I

11:15 AM–2:03 PM, Monday, March 5, 2007
Colorado Convention Center Room: 502

Sponsoring Units: FIAP DMP
Chair: Mike McGehee, Stanford University

Abstract ID: BAPS.2007.MAR.B39.10

Abstract: B39.00010 : Hybrid Tandem Solar Cells: CIGS/DSC with Carbon Nanotube Interlayer

1:51 PM–2:03 PM

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Authors:

  anvar Zakhidov
    (UTD-Nanotech Institute)

  William Shafarman
    (Institute Energy Convertion, University of Delaware,)

  Mei Zhang
    (UTD-NanoTerch Institute)

  Shaoli Fang
    (UTD-Nanotech Institute)

  Ray Baughman
    (UTd-Nanotech Institute, TX75070)

Multi-junction solar cells enable harvesting of wider regions of the solar radiation spectrum leading thereby to increased overall efficiencies. We present here a first study of a hybrid monolithic structure composed of\textit{ dye sensitized solar cells (}DSCs) with thin film inorganic CIGS$.$ We have created several architectures of monolithic multi-junction cells and address fundamental connectivity issues by using sheets of strong, transparent carbon nanotubes (T-CNTs) recently produced at UTD [1] as a uniform interlayer platform. Free-standing T-CNT networks can be laminated onto any surface and their advanteges as transparent interlayers in tandems is shown here for a tandem in which a un-finished CIGS ( top ITO is absent) is coated by T-CNTs. Such CIGS with T-CNT shows Voc=0.6 V and Isc $\sim $ 10 mA/cm2. It has been combined with DSC playing role of a photoactive counter-electrode, with iodine based electrolyte and Ru-dye on TiO2 mesoscopic electrode. The tandem demonstrated Voc= 0.82 V, which is higher than Voc of our sole DSC-CNT and Isc= 1mA/cm2, smaller than photocurrent of single DSC due to unbalanced current. The physics of processes of charge recombination in hybrid tandems is discussed . [1] M. Zhang, S. Fang, A. Zakhidov, S. B. Lee, A. Aliev, R.H. Baughman, \textbf{\textit{Science,}} 309,(2005) 1215

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2007.MAR.B39.10