Session B20: Focus Session: Properties of Ferroelectrics and Relaxors
11:15 AM–2:15 PM, Monday, March 5, 2007
Colorado Convention Center Room: 105
Sponsoring Unit:
DMP
Chair: Hans Christen, Oak Ridge National Laboratory
Abstract ID: BAPS.2007.MAR.B20.11
Abstract: B20.00011 : NMR Observation of Impurity-Pair Ordering in Weakly Disordered Solid Solutions
1:39 PM–1:51 PM
Preview Abstract
MathJax On | Off 
Abstract 
Authors:
David Ailion
(University of Utah, Department of Physics)
Bostjan Zalar
(J. Stefan Institute, Ljubljana, Slovenia)
Andrija Lebar
(J. Stefan Institute, Ljubljana, Slovenia)
Breaking of the average cubic symmetry in Li-doped potassium tantalate (K$_{1-x}$Li$_{x}$TaO$_{3})$ was observed with quadrupole-perturbed $^{7}$LiNMR at temperatures (150-400 K) far above the nominal glass transition temperature (80 K). The observed spectrum consists of contributions from both isolated Li ions (i.e., with no nearest neighbor Li) and from Li pairs. The isolated Li ions move among six equivalent off-center sites in a potential having cubic symmetry. These have zero average electric-field gradient and, hence, exhibit no quadrupole splitting. In addition, very low intensity, but well resolved, quadrupole satellites having a temperature-dependent splitting were observed. This splitting indicates that the various Li pair configurations are not all equally probable. These are the first observations of biased Li-ion ordering that persists in the paraelectric phase at temperatures high above the glass phase.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2007.MAR.B20.11