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Session B15: Focus Session: Inorganic Glasses

11:15 AM–2:03 PM, Monday, March 21, 2005
LACC Room: 405

Sponsoring Unit: FIAP
Chair: John Kieffer, University of Michigan

Abstract ID: BAPS.2005.MAR.B15.7

Abstract: B15.00007 : The self-organization window in (Na$_{2}$O)$_{x}$(B$_{2}$O$_{3}$)$_{1-x}$ glasses

1:15 PM–1:27 PM

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Authors:

Vamsikrishna Rompicharla
T. Qu
P. Boolchand
W. Huff
(Univ. of Cincinnati)

T-modulated DSC measurements on dry sodium borate glasses show T$_{g}$(x) to display a global maximum near x $\sim \quad \raise.5ex\hbox {$\scriptstyle 1$}\kern-.1em/ \kern-.15em\lower.25ex\hbox{$\scriptstyle 4$} $ , and the non-reversing enthalpy ($\Delta $H$_{nr}$(x)) to show a square- well like deep and flat global minimum ($\sim $0) in the 0.27 $<$ x $<$ 0.36 range-the \textit{reversibility window}. In analogy to the work on chalcogenide glasses, we identify borate glasses at x $<$ 0.27 to be stressed-rigid, those in the \textit {reversibility window} to be intermediate and those at x $>$ 0.36 to be floppy. The \textit{reversibility window} correlates well with a maximum in packing fraction$^{1}$ deduced from mass density results and with a maximum in concentration of isostatically rigid diborate structural groupings in NMR$^{2}$. Optical transmission of polished platelets examined with a polarizing microscope show \textit{window compositions} to be optically transparent and clear, while those outside the window at x $<$ 0.27 and at x $>$ 0.36 to show dark spots of increasing density as one goes away from the window compositions. The spotting reflects birefringence due to stress accumulation. These results confirm that intermediate phases occur in oxide- as in chalcogenide- glasses and form space filling and stress-free or self-organized networks. \newline \newline 1. Steve Feller (private communication). \newline 2. G.E.Gellison and P.J.Bray, JNCS 29, 187(1978). \newline Supported by NSF grant DMR 04-56472. \newline

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2005.MAR.B15.7