Session G26: Minisymposium: Electrokinetic Flows about Ion-Selective Surfaces
8:00 AM–10:10 AM, Monday, November 21, 2011
Room: 329
Chair: Udi Yariv, Technion - Israel Institute of Technology
Abstract ID: BAPS.2011.DFD.G26.4
Abstract: G26.00004 : Concentration Polarization and Nonequilibrium Electro-osmotic Instability at an Ion-Selective Surface Admitting Normal Flow
9:18 AM–9:44 AM
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Abstract 
Author:
Aditya Khair
(Chemical Engineering Department, Carnegie Mellon University, Pittsburgh PA )
We revisit and build upon on the prototypical problem of ion transport across a flat ideal ion-selective surface. Specifically, we examine the influence of imposed fluid flows on concentration polarization (CP) and electrokinetic instability at over-limiting currents. We consider an ion-selective surface, or membrane, that admits a uniform flow across itself. The membrane contacts an electrolyte, whose concentration is uniform in a well-mixed region at a prescribed distance from the membrane. A voltage across the system drives an ionic current, leading to CP in the ``unstirred layer'' between the membrane and well-mixed bulk. The CP reflects a balance between advection of ions with the ``normal flow'' and diffusion. A Peclet number, Pe, parameterizes their relative importance; note, Pe is signed, as the flow can be toward or away from the membrane. An asymptotic analysis for thin Debye layers reveals a nonlinear CP profile, in contrast to the familiar linear profile at Pe=0. Next, we consider over-limiting currents, wherein a non-equilibrium space-charge layer emerges near the membrane surface. Finally, we examine the instability of the quiescent concentration polarization due to second-kind electro-osmosis in the space-charge layer. A stability analysis shows that the imposed normal flow can enhance or retard the instability, depending on its direction.
To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2011.DFD.G26.4