Session L1: Poster Session II (4:00 pm - 6:00 pm)

4:00 PM–4:00 PM, Wednesday, June 15, 2011
Room: Atrium Ballroom BC


Abstract ID: BAPS.2011.DAMOP.L1.141

Abstract: L1.00141 : Photo-multidetachment and Fragmentation of C$_{60}^-$

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Authors:

  R.C. Bilodeau
    (Western Michigan U., Kalamazoo MI)

  M. Hoener
    (Western Michigan U., Kalamazoo MI)

  N. Berrah
    (Western Michigan U., Kalamazoo MI)

  S. Schippers
    (Justus-Liebig-Universitat, Giessen)

  A. M\"{u}ller
    (Justus-Liebig-Universitat, Giessen)

  D.A. Esteves
    (U. of Nevada, Reno NV)

  R. Phaneuf
    (U. of Nevada, Reno NV)

  N.D. Gibson
    (Denison U., Granville OH)

  C.W. Walter
    (Denison U., Granville OH)

  A. Aguilar
    (LBNL-ALS, Berkeley CA)

  J.M. Rost
    (Max-Planck-Institut, Dresden)

Absolute single-photon multi-detachment and fragmentation cross sections of C$_{60}^-$ fullerene anions have been measured as a function of energy with the merged ion-photon beam apparatus at the ALS. Multiple electron ejection was substantial at all photon energies, allowing product charge states up to C$_{60}^{3+}$ to be measured. We argue that $q$-fold detachment spectra of C$_{60}^-$ relate directly to $q$-fold ionization of neutral C$_{60}$, except the loosely bound excess electron of C$_{60}^-$ results in a significant change of the energy scale and increase of the absolute cross section, with otherwise little change in the structure. Fragmentation into cations of C$_{58}$ and C$_{56}$ was also studied. We conclude from the determination of appearance thresholds that fragmentation occurs at significantly lower photoexcitation energies in C$_{60}^-$ than in C$_{60}$.

To cite this abstract, use the following reference: http://meetings.aps.org/link/BAPS.2011.DAMOP.L1.141